PI High Temperature Resistant Base Film

    • Product Name: PI High Temperature Resistant Base Film
    • Chemical Name (IUPAC): poly(4,4'-oxydiphenylene-pyromellitimide)
    • CAS No.: 25322-99-0
    • Chemical Formula: (C22H10N2O5)n
    • Form/Physical State: Rolls
    • Factroy Site: Lingwu, Yinchuan, Ningxia, China
    • Price Inquiry: sales2@liwei-chem.com
    • Manufacturer: Anhui Liwei Chemical Co.,Limited
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    Specifications

    HS Code

    763685

    Material Polyimide (PI)
    Thickness Standard range 12μm to 125μm
    Color Amber/Gold (typical), Transparent, Black
    Tensile Strength ≥ 150 MPa
    Elongation At Break 40%-60%
    Temperature Resistance Up to 400°C (short term), 260°C (long term)
    Dielectric Strength 100-250 kV/mm
    Water Absorption < 2.0%
    Chemical Resistance Excellent (resistant to acids, alkalis, and solvents)
    Surface Roughness ≤ 0.05 μm
    Flame Retardancy UL94 V-0
    Thermal Expansion Coefficient 20-55 x 10^-6 /K
    Volume Resistivity > 1 x 10^16 Ω·cm
    Transparency 80%-90%
    Hardness Shore D70-85
    Material Polyimide (PI)
    Color Amber
    Thickness Customizable (typically 7.5-250 microns)
    Width Customizable (commonly up to 1040 mm)
    Length Customizable (typically roll form)
    Tensilestrength ≥135 MPa
    Elongation ≥45%
    Thermalresistance Up to 400°C
    Dielectricstrength ≥100 kV/mm
    Surfaceresistivity ≥10^16 Ω·cm
    Waterabsorption <2.5%
    Flameretardancy UL94 V-0
    Transparency 40-90% (depending on thickness)
    Dimensionalstability Excellent at high temperatures
    Solventresistance Excellent

    As an accredited PI High Temperature Resistant Base Film factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing PI High Temperature Resistant Base Film is packaged in rolls, 100 meters per roll, sealed in protective plastic and sturdy cardboard boxes.
    Container Loading (20′ FCL) Container Loading (20′ FCL) for PI High Temperature Resistant Base Film: 8-10 metric tons, securely palletized, moisture-protected, optimized for stability.
    Shipping The shipping of PI High Temperature Resistant Base Film involves secure packaging to prevent damage and contamination. The material is typically rolled, sealed in moisture-proof bags, and packed in sturdy cartons. Transportation occurs via climate-controlled carriers to maintain product integrity, with clear labeling for safety and handling requirements.
    Storage PI High Temperature Resistant Base Film should be stored in a cool, dry, and well-ventilated area, away from direct sunlight, moisture, and sources of heat. Keep the film in its original packaging to prevent contamination and physical damage. Maintain storage temperatures below 30°C and relative humidity below 70% to preserve its properties and performance. Avoid contact with incompatible chemicals.
    Shelf Life The shelf life of PI High Temperature Resistant Base Film is typically 12 months when stored in cool, dry, and original packaging.
    Application of PI High Temperature Resistant Base Film

    High Temperature Stability: PI High Temperature Resistant Base Film with stability temperature up to 400°C is used in flexible printed circuits, where it ensures consistent electrical insulation under extreme thermal conditions.

    Dimensional Stability: PI High Temperature Resistant Base Film featuring low thermal expansion coefficient is used in electronic display panels, where it maintains precise alignment during processing.

    Electrical Insulation: PI High Temperature Resistant Base Film with dielectric strength greater than 200 kV/mm is used in high-voltage insulation tapes, where it prevents electrical breakdown and increases operational safety.

    Chemical Resistance: PI High Temperature Resistant Base Film with high resistance to acids and alkalis is used in lithium-ion battery separators, where it prolongs component lifespan by minimizing chemical degradation.

    Mechanical Strength: PI High Temperature Resistant Base Film with tensile strength above 200 MPa is used in aerospace composite structures, where it enhances overall durability and mechanical robustness.

    Thickness Uniformity: PI High Temperature Resistant Base Film with thickness tolerance within ±1 μm is used in microelectronic fabrication, where it contributes to device miniaturization and consistent performance.

    Optical Clarity: PI High Temperature Resistant Base Film with light transmittance over 90% is used in optoelectronic displays, where it supports high-definition image quality and efficient light utilization.

    Flame Retardancy: PI High Temperature Resistant Base Film with UL 94 V-0 rating is used in automotive electronics, where it minimizes fire risks and complies with safety standards.

    Free Quote

    Competitive PI High Temperature Resistant Base Film prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please contact us at +8615380400285 or mail to sales2@liwei-chem.com.

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    Tel: +8615380400285

    Email: sales2@liwei-chem.com

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    Certification & Compliance
    More Introduction

    PI High Temperature Resistant Base Film: A Closer Look from the Manufacturer’s Perspective

    Understanding Our PI High Temperature Resistant Base Film

    PI high temperature resistant base film is a product we spent years refining to support advanced electronics, flexible displays, and insulation for motor and transformer industries. Our experience as chemical manufacturers sits at the core of every roll we deliver, and we’ve learned that true reliability begins with uncompromising attention to raw materials and process control. Polyimide (PI) film, due to its aromatic imide backbone, provides the kind of heat stability and dimensional control our customers demand from high-stress environments—conditions where lesser plastics deform, discolor, or crack apart. In our production process, we use a clean-room-controlled system to avoid pinholes and contaminants that compromise insulation grade and mechanical properties. This process also assures the rich, uniform golden-brown color so many engineers recognize in quality film.

    Tuning Performance to Modern Application Needs

    Our product comes in models such as PI-6051 and PI-5052, with thickness options ranging from 7.5 to 125 microns. These figures aren’t picked at random; they follow direct feedback from clients across electronics, electric vehicles, and aerospace. For circuit board manufacturing, thin films support lamination while maintaining adhesive compatibility. In flexible printed circuits, a 25-micron grade balances flexibility with puncture resistance. For insulation on busbars and coils, we manufacture thicker films up to 125 microns, providing confidence that breakdown voltage remains high even after repeated heat cycling.

    Through direct contact with electronic assembly technicians, we’ve pursued continuous improvement—learning, for example, that minor pinhole defects lead to early device failures. That problem led us to increase investment in optical inspection, which now includes full-width scanning on every lot. We measure properties like dielectric strength, elongation at break, and tensile modulus, but the real benchmark comes after our rolls see a run through solder reflow or several years in a transformer winding. Companies who build their own capacitors started sharing firsthand results from field trials: they reported a significant drop in insulator replacement rates when shifting from commodity films to our high-end PI base film.

    Application Experience: Not All Films Behave the Same

    It’s one thing to read numbers in a data sheet; it’s another to see real-world differences in how materials stand up to stress. Polyimide’s aromatic backbone resists thermal oxidation—something crucial in repeated thermal cycles, such as those seen in wave soldering or continuous operation inside induction motors. PET films, the closest common alternative, begin noticeably shrinking at 150°C and lose their mechanical strength beyond that point. PI films routinely perform at 200–260°C, with exposure to 400°C during soldering causing minimal property shifts.

    Compared to PEN and PTFE films, PI base film offers better adhesion to copper and aluminum claddings, which helps reduce delamination failures in multilayer flexible circuits. Films used in industry are often chosen by cost alone, but customers who worked with both PET and polyimide shared that PI’s flame resistance and dielectric properties were the only way to meet modern low-profile insulation requirements for next-generation battery packs.

    In electric vehicles, manufacturers need high dielectric strength over prolonged exposure to rapidly cycling temperatures. PI film delivers consistent resistance to corona discharge—a result of the polymer’s natural aromatic stability. This feedback hasn’t just shaped adjustments to our resin synthesis; it confirmed that durability in relentless automotive and industrial environments can’t be negotiated.

    Quality Control and Repeatability

    We learned early on that the smallest variance in molecular weight or thermal imidization leads to surface voids and reduced yield. That lesson came from a high-profile coil manufacturer who returned a full batch after finding micro-cracks post-annealing. Rather than digging into contracts, we focused on process control, revising our solvent casting stages for more uniform evaporation and denser polymer formation. Today, every lot passes both dimensional stability and mechanical strength checks at elevated temperatures. From customer feedback on coil winding, we know that films with too much residual solvent stretch or warp—so by investing in enhanced solvent recovery and secondary baking ovens, we have reduced batch-to-batch deviation below two percent.

    Surface flatness also plays a part when integrating thin polyimide film in optical or photovoltaic modules. We maintain strict roll-to-roll tension management, and reject any roll showing camber or telescoping issues. These controls translate into real savings: less downtime for our customers, fewer complaints, and better integration with pick-and-place automation.

    Handling, Processing, and the Realities of Scale

    Manufacturing at scale brings its own quirks. For example, scaling-up to thousands of square meters increases the temptation to cut corners. Our decision to keep incoming quality inspection of monomers and diamines—rather than simply checking the end product—came after realizing that contaminated feedstock pushed downstream yields down ten percent in one quarter. Feedback from a film capacitor client, who saw a drop in insulation performance, helped us trace the problem back to upstream raw material purity. In this case, simply passing end-point checks wasn’t enough. So now, every batch is tracked from monomer to film roll, including resin viscosity logs, infrared spectra, and roll mapping.

    On the shop floor, roll handling is critical. Polyimide is less forgiving than PET or PVC films in terms of scratch resistance during slitting. Technicians who use our films in tape lines described surface scoring issues with lower-cost alternatives. Our team responded by collaborating with slitter OEMs and adjusting both knife angle and film winding tension—fine details which translate into surface integrity, less waste in adhesive coating lines, and better yields for end customers converting film into pressure-sensitive tapes.

    Small changes in how a roll is stored or transported can create big failures down the line. PI film absorbs very little moisture, but the payoff comes only with proper packaging. We adopted multi-layer aluminum foil packaging to avoid micro-contamination, especially for thin-film optics customers requiring defect-free surfaces.

    Markets Pushed by Technical Requirements

    Each market carved out unique expectations. Semiconductor packaging customers demanded process cleanliness, not just film thickness. Our regular visits to their cleanrooms helped retool our air filtration systems and altered staff dress codes to reduce surface defects. Aerospace engineers emphasized traceability and outgassing performance. Film in satellite circuits must deliver high dielectric strength with zero outgassing up to 200°C. We beefed up our outgassing screening, including additional thermal vacuum exposure, after learning from a low-Earth orbit module integrator that stray volatiles left haze deposits on critical sensors.

    Consumer electronics kept pushing for thinner, more flexible film that doesn’t lose strength during laser ablation. That feedback loop saw us investing in resin modifications for improved cut edge stability, helping brands shift to finer circuit geometries. The trend toward foldable screens led us to develop grades passing 300,000 flex cycles, with independent test houses confirming that flexural cracks stayed under critical threshold values.

    Power transmission and distribution drive demand for the thicker grades, where a single flaw in insulation could lead to catastrophic transformer failures. We spent years collecting data from utilities who tracked our film performance across thousands of installed units, correlating breakdown voltages after a decade of service. Their results showed failure rates significantly lower than standard aramid or modified cellulose solutions, and their feedback shaped our approach to continuous process improvement.

    Innovation Backed with Practical Experience

    Looking back, countless innovations in our PI base film emerged from listening to both junior technicians and senior engineers wrestling with day-to-day production stress. A recurring problem involved microbubbles trapped during tape coating, leading to adhesive pick-off on high-speed lines. To address this, we fine-tuned our film surface tension and cleanliness, logging and responding to every process deviation at the slitting and packaging stages to reduce the frequency of this problem.

    Expansion into transparent flexible electronics led to tightening impurity controls—adapting resin purification methods to drive down haze levels—which paid off in lower rejection rates for manufacturers of display modules.

    Achieving high-volume medical device approval required passing a battery of cytotoxicity and extractables tests, but the toughest part came in maintaining repeatability across hundreds of lots. By pushing for an electronically logged batch history, we enabled our clients to map device failures (should they ever occur) down to the reel.

    How PI High Temperature Resistant Base Film Stands Apart

    Some companies see film simply as a commodity, looking for minor price cuts. Our business stays focused on how real-world performance trumps cost in any mission-critical application. Unlike PET, which breaks down and melts at lower temperatures, PI film stands strong under prolonged thermal exposure. Where PTFE offers high temperature resistance with low surface energy, PI combines chemical durability with superior electrical insulation and better adhesion, a key for electronics. Our film also resists UV, radiation, and solvents—properties confirmed in destructive lab and field tests. The difference lies not just in chemistry but also in strict process discipline, consistent thickness down to the micron, and full traceability that customers have come to trust during audits.

    In electronics assembly, circuit flexibility without failure means trusting that even after hundreds of flex cycles or thermal shocks, the insulation won’t degrade. Our film’s low water absorption means dimensional changes stay minimal, supporting components where precision alignment is critical. For windings in high-power transformers, long-term exposure to fluctuating voltages and temperatures tests the strength of every roll. Industry data and field results reveal that polyimide, properly formulated and converted, outlasts alternatives—something we back up both with lab results and long-term customer partnerships.

    Companies in high-growth areas like 5G, electric vehicles, and advanced robotics continue to redefine the boundaries for what a high temperature film must survive. Our direct support, combined with regularly updated test data, helps manufacturers tune their own assembly lines with confidence—instead of betting on untested alternatives.

    Continuous Customer Feedback Drives Progress

    Successful manufacturing isn’t about making a product and sending it off. The real proof comes from working side-by-side with our users through their own evolving challenges. Field engineers installing busbar insulation in megawatt battery installations shared practical tips on improving slot performance and adhesive compatibility—insights impossible to pick up in a lab alone. Technicians on high-speed lamination lines described how thicker films, insufficiently annealed, produced dust and curled during application. Adjustments in our post-cure protocols fixed that, reducing lamination times and waste. These hands-on experiences improved the fine points in our manufacturing process, like optimal post-anneal tensioning and antistatic film dust covers.

    Printed circuit board fabricators needing laser ablation and adhesive patterning saw better control with our specially primed PI film grades. Schools and research labs, often on tight budgets, used our smaller lots to troubleshoot process ideas before scaling up. From pre-sales technical workshops to fast-turn around for sample requests, sharing expertise keeps us learning beyond the routine of manufacturing alone.

    The customer-driven approach means staying responsive to repair rates, product recalls, and in-field technical feedback. Our team remains open to pilot production runs, new resin modifications, or adjusting curing cycles based on joint test outcomes. Whether it’s sharing best practices in process control or learning about new breakdown modes not found in textbooks, the give-and-take with engineers and technicians in the field drives our development roadmap.

    Environmental and Regulatory Commitments

    Environmental regulations keep tightening each year, affecting both process chemistry and product formulation. Our factory complies with strict emission and solvent recovery requirements. We cut volatile organic compound emissions by more than half by upgrading our exhaust recovery and switching to lower-impact solvents during imidization. For clients who export globally, we certify compliance with RoHS and halogen-free standards. By transitioning to cleaner energy sources in part of our production, we reduced our carbon footprint—and learned that energy-efficient imidization doesn’t have to compromise film quality.

    For sensitive applications, such as medical devices or food packaging, we control non-intentionally added substances below regulatory thresholds. Customers auditing our lines often prioritize transparency. We keep digital batch records and provide full disclosure on raw material origins, coating chemicals, and cleaning protocols. This level of visibility reassures customers—especially those facing increasingly stringent end-user documentation demands.

    The Path Forward: Continuous Evolution

    Making PI high temperature resistant base film isn’t just about chemistry. Our team’s willingness to analyze complaints, experiment with fine resin adjustments, and invest in process automation keeps us competitive. We regularly meet with users from battery manufacturers, aerospace engineers, and electronics assembly technicians, drawing on their experiences to reshape our development strategies. Over time, we witnessed clients shift from commodity polyester films, dealing with frequent breakdowns and time-consuming recalls, to relying on polyimide for durable protection. With each feedback round, whether it’s improving film tracking for traceability or adjusting slitting methods for cleaner edges, we integrate these learnings back into manufacturing.

    New technologies such as foldable devices, miniaturized energy storage, and next-generation RF chips place increasing strain on base film properties. Staying close to those pushing the boundaries ensures our PI film evolves to support the most demanding modern applications. Direct engagement, long-term product tracking, and total process control translate into films that electrical, electronics, and industrial manufacturers can depend on year after year.

    Our commitment won’t end with the current generation of products—customer partnership and technical feedback will always drive improvements, and every roll we ship reflects not just a polymer chain, but the cumulative knowledge of everyone shaping our manufacturing process from start to finish.